This query will give the values of the profile option set at different level. Use the profile option name or user profile option name which you see in the front end.
SELECT user_profile_option_name,SUBSTR(e.profile_option_name,1,25) PROFILE
,DECODE(a.level_id,10001,'Site',10002,'Application',10003,'Resp',10004,'User') "Level"
,DECODE(a.level_id,10001,'Site',10002,c.application_short_name,10003,b.responsibility_name,10004,d.user_name) LValue
,NVL(a.profile_option_value,'Is Null') Value
,SUBSTR(a.last_update_date,1,25) UPDATED_DATE
FROM fnd_profile_option_values a
, fnd_responsibility_tl b
, fnd_application c
,fnd_user d
, fnd_profile_options e
, fnd_profile_options_tl f
WHERE 1=1
AND f.user_profile_option_name in ('&User_Profile_Name')
AND e.profile_option_id = a.profile_option_id AND a.level_value = b.responsibility_id (+)
AND a.level_value = c.application_id (+) AND a.level_value = d.user_id (+)
AND f.PROFILE_OPTION_NAME(+)=e.profile_option_name
ORDER BY e.profile_option_name;
Reference